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醋酸纤维素颗粒对主流烟气中焦油和苯酚释放量的影响

Influence of cellulose acetate particles on tar and phenol deliveries in mainstream cigarette smoke

  • 摘要: 分别以三乙酸甘油酯(TC)和羧甲基纤维素(CMC)为黏结剂,采用摇摆造粒工艺制备T型和C型醋酸纤维素(醋纤)颗粒,通过将颗粒置于滤嘴中并在ISO模式下抽吸卷烟,探索了烟支吸阻在同一水平下颗粒类型、颗粒粒径对主流烟气中焦油和苯酚释放量的影响,并根据不同颗粒添加量下对苯酚的吸附量比较了醋纤颗粒和醋纤滤棒对苯酚吸附能力的大小。结果表明:①醋纤颗粒的类型和粒径对焦油递送量的影响不明显,颗粒粒径对苯酚吸附能力的影响不明显;②T型和C型颗粒对苯酚的选择性吸附能力差异显著。T型颗粒每支卷烟添加量为25 mg时,单口苯酚释放量的选择性降低率>15.0%;C型颗粒对苯酚无明显的吸附能力;③单位质量T型颗粒对苯酚的选择性吸附能力低于单位质量醋纤滤棒。

     

    Abstract: In order to study the influences of cellulose acetate (CA) particles on tar and phenol deliveries in mainstream cigarette smoke, two types of CA particles (T-shaped and C-shaped) were prepared via swing granulation process with glyceryl triacetate (TC) and carboxylmethylcellulose (CMC) as adhesives, respectively. The CA particles of different types and sizes were embedded in cigarette filters of conventional cellulose acetate fibre, the deliveries of tar and phenol in mainstream smoke of cigarettes with the same draw resistance were determined under ISO smoking regime, and the effects of CA particle type and size were investigated. In addition, the adsorption abilities of CA particle and cellulose acetate filter to phenol were compared according to the mass of absorbed phenol determined at different adding rates of CA particles. The results showed that:1) The effects of CA particle type and size on tar delivery in mainstream cigarette smoke and that of particle size on phenol delivery were marginal. 2) The selective adsorption ability of T-shaped and C-shaped CA particles to phenol differed significantly; at the adding rate of 25 mg/cig., the selective reduction rate of T-shaped particles for phenol delivery was more than 15.0% at a single puff, while the adsorption ability of C-shaped particles to phenol was not obvious. 3) At per unit mass, the selective adsorption ability of T-shaped particle to phenol was lower than that of cellulose acetate filter.

     

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