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配方组成对碳质热源材料燃烧特性的影响

Effects of composition on combustion property of carbonaceous heat source material

  • 摘要: 为揭示配方组成对碳质热源材料燃烧特性的影响,利用密炼机制备了不同组成的碳质热源材料,并利用同步热分析仪(STA)和自制燃烧速率测定装置表征了不同配方碳质热源材料的燃烧特性。结果表明:①炭粉种类对热源材料燃烧失重过程有影响,同种炭粉其粒径越小,越容易燃烧;碳酸钙会延迟碳质热源材料的燃烧起点和过程,但使燃烧终点提前到达;低粒径石墨粉(500目、25 μm)分别延迟和加速热源材料低温阶段和高温阶段的燃烧失重,但大尺寸石墨粉(150目、106 μm)阻碍了热源材料的整个燃烧失重过程;纳米氧化铁、蒙脱土和钾盐均延迟了热源材料在高温下的燃烧失重过程,但钾盐可以加速低温阶段失重,钠盐则与钾盐效果相反。②加入小尺寸炭粉和氧化性助燃剂可有效提升热源材料的燃烧速率,而碳酸钙、石墨粉、非氧化性的钾钠盐、纳米氧化铁及蒙脱土均不同程度降低了热源材料的燃烧速率,其中最明显的是蒙脱土。

     

    Abstract: In order to investigate the influences of composition on combustion property of carbonaceous heat source material (CHSM), a series of CHSM with different compositions were prepared by an internal mixer, and their combustion properties were characterized by a synchronous thermal analyzer (STA) and a self-made burning rate meter. The results showed that:1) The type of carbon powder affected the mass loss process of combustion; carbon powder with smaller particle size combusted more easily. Calcium carbonate delayed both the starting point and whole process of combustion, and approached to the ending point of combustion earlier. Graphite powder with small particle size (500 mesh, 25 μm) delayed and accelerated the mass loss at low and high temperature stages, respectively. However, graphite powder with large size (150 mesh, 106 μm) hindered the whole mass loss process of combustion. Nano-Fe2O3, nano-montmorillonite and potassium salt in CHSM postponed the mass loss process of combustion at higher temperature. Potassium salt accelerated the mass loss at low temperature stage, while sodium salt was on the contrary. 2) The combustion rate of CHSM was effectively promoted by the addition of small size carbon powder and oxidative combustion promoter, while reduced to different extents by the addition of calcium carbonate, graphite powder, non-oxidative potassium and sodium salt, nano-Fe2O3 and nano-montmorillonite, especially nano-montmorillonite.

     

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