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温度与甘油对烟草颗粒热解及释烟特性的影响

Effects of temperature and glycerol on pyrolysis and smoke release of reconstituted tobacco particles

  • 摘要: 为揭示加热状态下烟草颗粒烟气释放规律,采用湿法造粒技术,利用热分析仪(TGA)和锥型量热仪(CONE)研究甘油添加量与温度对其热解和烟气释放特性的影响。结果表明:①添加甘油可降低烟草颗粒主要失重过程温度,增加低温下失重比例,并提高低温下失重速率。②增加甘油含量,烟草颗粒起始释烟速率增大,累积释烟总量增加,但过高的添加量(35%)会降低累积释烟总量;导热性较好的烟草样品释烟速率最大;甘油的添加降低了CO释放量,但与添加量的关系不明显。③升高温度,烟气释放速率增大,释烟过程缩短,累积释烟总量先增大后降低,温度过高(400℃)烟草颗粒发生燃烧;烟气中CO与CO2释放量随温度升高大幅增加,且两者释放规律与烟气释放规律一致。

     

    Abstract: In order to study the smoke release of tobacco particles under heating, a series of tobacco particles were prepared by wet granulation and the influences of glycerol and heating temperature on the thermal degradation and smoke release of the particles were investigated via thermogravimetric analysis and cone calorimetry respectively. The results showed that: 1) The addition of glycerol lowered the temperature of main weight loss process of tobacco particles in air, while increasing the rate and percentage of mass loss at low temperature. 2) The initial rate and total amount of smoke release increased with the increase of glycerol content. However, greater than 35% glycerol decreased the total release of smoke. Samples with the highest thermal conductivity had the maximum release rate of smoke. The addition of glycerol reduced the emission of CO, but the relationship between the addition rate and CO emission was not obvious. 3) Raising heating temperature accelerated smoke release rate and shortened the release process, while the total smoke release increased first and then decreased. Higher than 400 ℃ ignited tobacco particles. The releases of CO and CO2 increased significantly with the raise of temperature, and their release rules were similar to that of smoke release.

     

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