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滤棒特性对18种爆珠香味成分转移行为的影响

Influences of filter rod characteristics on transfer of 18 aroma components in breakable capsule

  • 摘要: 为研究爆珠香味成分在不同滤棒特性卷烟中的转移行为,通过建立18种香味成分的GC-MS/MS分析方法,剖析了爆珠放置位点、爆珠大小、滤棒空腔大小和烟支圆周等滤棒特性对18种爆珠香味成分转移行为的影响。结果发现:①在通风率为0的常规卷烟中,爆珠添加位点离烟丝端越近,越利于沸点小于300 ℃的香味成分向主流烟气的转移;爆珠粒径最小,18种香味成分的转移率也最小;滤棒空腔越大,沸点小于300 ℃的香味成分的转移率也越大。②相同粒径爆珠放置于不同圆周卷烟中时,18种香味成分的转移率均随着卷烟烟支圆周的增大而增大。③相关性分析表明,除N-乙基-L-薄荷基甲酰胺(WS-3)外,添加位点(距唇端的距离)、滤棒空腔和烟支圆周与其他17种香味成分的转移率均高度正相关,爆珠粒径与大部分香味成分的转移率高度或中度正相关。④层次聚类分析表明,爆珠香味成分的转移行为与化学成分本身的沸点、分子量和挥发性等物化性质也密切相关。

     

    Abstract: In order to study the transfer behaviors of 18 aroma components in breakable capsules to mainstream smoke of cigarettes with filter rods of different characteristics, the influences of filter rod characteristics, including the location and size of breakable capsule, the filter cavity size, and the circumference of cigarette, etc., were analyzed by a GC-MS/MS method. The results showed that: 1) For cigarettes with no ventilation, the closer the breakable capsule location to the tobacco end, the more beneficial to the transfer of aroma components with a boiling point of less than 300 ℃ would be. The transfer rates of the 18 aroma components decreased with the decrease of breakable capsule size, while those of the aroma components with a boiling point less than 300 ℃ increased with the increase of filter rod cavity size. 2) When the breakable capsules of the same size were embedded in cigarettes with different circumferences, the transfer rates of the 18 aroma components increased with the increase of cigarette circumference. 3) The correlation analysis indicated that the distance between the breakable capsule and mouth end of a cigarette, filter rod cavity size, and cigarette circumference highly positively correlated to the transfer rates of the 17 components except for N-ethyl-2-isopropyl-5-methylcyclohexanecarboxamide (WS-3), and the size of a breakable capsule highly or moderately positively correlated with the transfer rates of most of the aroma components. 4) Hierarchical clustering analysis suggested that the transfer behaviors of the aroma components in breakable capsules were closely correlated to their boiling points, molecular weights, volatility, and other physicochemical properties.

     

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