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桂叶油热解产物的GC/MS分析

Analysis of Pyrolysis Products of Cinnamon Leaf Oil by Gas Chromatography/Mass Spectrometer

  • 摘要: 采用GC/MS法分析了在250、300、400、500、600、700、800和900℃下桂叶油的热解产物,并用归一化法进行了定量。结果表明:①桂叶油在250℃以下不热解,丁香酚、β-石竹烯和乙酰丁香酚是桂叶油的主要致香成分;②600℃以下桂叶油主要释放出丁香酚和乙酰丁香酚等52种化合物;③700℃以上桂叶油不释放致香物质,而释放芳烃和稠环芳烃等有害物质,且其种类及相对含量均随着热解温度的升高而增大;④桂叶油的热解产物可能主要是丁香酚裂解形成的。

     

    Abstract: At 250,300,400,500,600,700,800 and 900℃,the pyrolysis products of cinnamon leaf oil were analyzed by gas chromatography/mass spectrometry,and the relative content of the pyrolysis products were also calculated by normalization method.The results indicated that:1)cinnamon leaf oil was not pyrolysised at 250℃,and released out of flavor substances,such as eugenol,β-caryophyllene and aceteugenol;2)under 600℃,52 pyrolysis products were released from the essence;3)above 700℃,no flavor was found in the pyrolysis products.Furthermore,with the raise of pyrolysis temperature,harmful substances were released,such as aromatic,polycyclic aromatic hydrocarbons;and the category and relative content of them increased with the temperature;4)the pyrolysis products of cinnamon leaf oil were mainly possible came from eugenol.

     

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