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卷烟烟丝热裂解产物香味成分分析

Analysis of Aromatic Components in Pyrolytic Products of Cut Tobacco

  • 摘要: 为了解热裂解温度对烟气香味成分的影响,将烤烟型卷烟烟丝于温度50℃(20s)???400、600、800、1000、1200℃(20s)和空气(流速30mL/min)中进行了热裂解,并对裂解产物中的香味成分进行GC/MS分析。结果表明:①400、600、800、1000和1200℃下的热裂解产物中分别鉴定出57、70、76、77和68种香味成分;②香味成分的释放量随着热裂解温度升高而增大:400→600℃增幅达24%,600→800℃增幅约为1%,800→1000℃增幅为8%,1000℃时释放量达到最大,而后降低;③不同热解温度对应的最大释放量的香味组分分别为:400℃下呋喃酮和吡喃酮类、醛类、酚类、醇酸酯类,600℃下烯烃类、烟碱,800℃下麦斯明与二烯烟碱等烟碱类,1000℃下酮类、氮杂环类、呋喃及苯并呋喃类;④400~600℃,烟碱的释放量随着热解温度的升高而增大,至600℃达到最大,而后下降,但降幅不大。卷烟烟气的香味可能随燃吸温度而变化。

     

    Abstract: In order to investigate the effects of pyrolytic temperature on the aromatic components in cigarette smoke,the cut filler of Virginia type cigarette was pyrolyzed in an air flow of 30 mL/min at the programming temperatures started from 50℃ for 20 s and then increased to 400℃,600℃,800℃,1000℃ and 1200℃ at the rate of 10℃/ms respectively,and held at the end temperature for 20 s.The aromatic components in pyrolytic products released at different pyrolytic conditions were analyzed by gas chromatography/mass spectrometry.The results showed that:1)57,70,76,77 and 68 kinds of aroma components were identified in the pyrolyzates at 400℃,600℃,800℃,1000℃ and 1200℃,respectively;2) the deliveries of aromatic components increased with the increase of pyrolytic temperature from 400℃ to 1000℃,increased by 24% from 400℃ to 600℃,by 1% from 600℃ to 800℃,by 8% from 800℃ to 1000℃,and decreased from 1000℃ to 1200℃;3) the dominant aromatic components at different pyrolytic temperatures were:furones and pyrones,aldehydes,phenols,alcohols,acids and esters at 400℃,alkenes and nicotine at 600℃;nicotine derivatives including myosmine,nicotyrine,etc at 800℃;ketones,nitrogen heterocyclics,furans and benzofurans at 1000℃;4) nicotine delivery increased with the increase of pyrolytic temperature in the range of 400℃ to 600℃,and decreased slightly thereafter.It seemed that the flavor of cigarette smoke would change with burning temperature.

     

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