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卷烟烟气中烟草特有亚硝胺的滤嘴截留效率测定

Determination of Filtration Efficiencies of Filters to Tobacco-specific Nitrosamines in Cigarette Smoke

  • 摘要: 为考察烟草特有亚硝胺(TSNAs)的滤嘴截留效率(FE),建立了采用GC-TEA测定卷烟滤嘴中TSNAs截留量的方法,并采用该方法测定了同一醋纤滤嘴卷烟样品在ISO,Massachusetts,WG9-A,WG9-B,WG9-C和Health Canada 6种抽吸方案下的FEs,以及在ISO方案下醋酸纤维滤嘴、聚丙烯纤维滤嘴和活性炭+醋酸纤维复合滤嘴的FEs。结果表明:①不同类型滤嘴中截留的TSNAs的回收率均在90%~110%之间,相对标准偏差(RSD)均小于8%;②随着抽吸方案由ISO转变为其他抽吸方案,主流烟气TSNAs释放量和滤嘴截留量增加,而4种TSNAs的滤嘴截留效率则相对稳定,RSD均<5%;③3种不同类型的滤嘴对TSNAs的截留效率比较接近。

     

    Abstract: In order to investigate the filtration efficiencies(FEs) of cigarette filters to 4 kinds of tobaccospecific nitrosamines(TSNAs) in cigarette smoke, a method based on GC-TEA was developed. The FEs of the same cellulose acetate(CA) filter cigarette samples were determined with the developed method under six smoking standards, including ISO, Massachusetts, WG9-A, WG9-B, WG9-C and Health Canada regimes, and the FEs of cigarette samples with different filters, CA, polypropylene(PP) and active carbon combined with CA filters, were also determined under ISO regime. The results showed that:1) the recoveries of TSNAs trapped in different filters ranged from 90% to 110% with relative standard deviations(RSD) of less than 8%; 2) although the TSNAs deliveried by mainstream smoke and retained by filters increased as smoking regime shifted from ISO to the other standards, the FEs to 4 TSNAs were relatively unchanged with RSDs of less than 5%; 3) the FEs of the 3 types of filters to TSNAs were similar.

     

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