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烤烟烟叶叶片及其烟梗的热分解过程和动力学

Comparison of Pyrolysis Process and Kinetics Between Tobacco Lamina and Stem with Thermogravimetric Analysis

  • 摘要: 为了解烟叶叶片及其烟梗的热分解特性,采用热重分析研究了烤烟烟叶叶片和烟梗样品在氧化气氛中的热分解过程,并运用Coats-Redfern法和Malek法对样品在经历了吸附水的蒸发过程以后的各热失重阶段进行了动力学分析。结果表明:①叶片样品的热分解主要包括5个热失重阶段,而烟梗则表现为9个热失重阶段;②除了在吸附水的蒸发和烟草生物聚合物的热氧化降解阶段有相似的质量损失率外,两种样品其余的各失重阶段的质量变化明显不同;③两种样品的大部分热失重过程可用F1动力学模型进行模拟;与叶片样品相比较,除热氧化降解阶段具有相同的活化能外,其余各阶段烟梗具有更高的动力学参数。

     

    Abstract: In order to investigate the pyrolysis properties of tobacco lamina and stem, their pyrolysis processes in an oxidative atmosphere were studied with thermogravimetric analysis, and the kinetic analysis of each thermal weight loss phase after the evaporation of adsorbed water was conducted with Coats-Redfern and Malek methods. The results showed that:1) The pyrolysis process of lamina mainly included five different phases, while nine different phases were observed in the pyrolysis process of stem. 2) At the adsorbed water evaporation phase and thermo-oxidative degradation phase of biological polymer, lamina and stem had similar weight loss rate, but the weight change rates at the other phases were obviously different. 3) Most of thermal weight loss phases of lamina and stem could be simulated by F1 kinetic model. Comparing with lamina, stem featured higher kinetic parameters at most phases, but thermo-oxidative degradation phase when their activation energies were similar.

     

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