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D-木糖和L-精氨酸模型体系棕色化反应产物的研究

  • 摘要: 制备了D-木糖和L-精氨酸在不同反应条件下(pH、反应时间和物料摩尔比)的模型体系棕色化反应产物,研究了反应条件对反应产物性质(颜色强度和在卷烟中的加香效果)的影响。对加入棕色化反应产物的卷烟进行评吸认为,等摩尔的D-木糖和L-精氨酸在pH=7、反应3小时的反应产物具有明显的加香效果。采用气相色谱和质谱分析该反应产物的醚溶性成分,表明主要成分为具有焦甜香的呋喃类化合物。

     

    Abstract: The model browning reaction products derived from the D-xylose and L-arginine (MRPXA) were prepared under different reaction conditions (pH, reaction time and molar ratio of reactants).The effects of reaction condition on the properties of MRPXA(color intesity, antioxidative effect on soybean oil and organoleptic evaluation of the treated cigarettes)were investigated.It was observed that the MRPXA had strong antioxidative effect on soybean oil.The cigarettes treated with MRPXA, prepared by reacting equimolar amounts of D-xhlose and L-arginine at pH 7 for 3h, were found to be significantly better than the contral cigarettes by the panel.The ether-soluble compounds of the reaction product were further analyzed by gas chromatography and mass spectrumetery.The analytical results showed that the major identified components were furan compounds, which gave a characteristic burnt-sugar note.

     

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